Properties in CO Hydrogenation of the Nano-Catalysts Produced by Supporting Iron Carbonyls on SiO2
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URI (для ссылок/цитирований):
https://elib.sfu-kras.ru/handle/2311/833Автор:
Kuznetsov, Boris N.
Kovalchuk, Vladimir I.
Mikova, Nadezhda M.
Chesnokov, Nikolai V.
Naimushina, Liliya V.
(Boris N. Kuznetsov, Nikolai V. Chesnokov: Siberian Federal University,
79 Svobodny, Krasnoyarsk, 660041 Russia, Institute of Chemistry and Chemical Technology SB RAS,
Akademgorodok, Krasnoyarsk, 660036 Russia, e-mail: bnk@icct.ru; Vladimir I. Kovalchuk: Pittsburg University, PA 15261 USA; Nadezhda M. Mikova: Institute of Chemistry and Chemical Technology SB RAS,
Akademgorodok, Krasnoyarsk, 660036 Russia; Liliya V. Naimushina: Krasnoyarsk State Institute of Economics and Trade,
2 L. Prushinskaya st., Krasnoyarsk, 660075 Russia)
Дата:
2008-11Аннотация:
There have been studied the catalytic properties in the reaction of CO hydrogenation of nano-catalysts
produced by supporting on silica the iron carbonyl compounds containing various numbers of metal
atoms. It was determined that the catalytic activity of the supported carbonyls increases with the rise
of the number of the metal atoms in their composition. Some of them have a very high selectivity in
respect to the C2-C3 olefins.