Author | Trofimchuk, A. K. | |
Author | Didukh, S. L. | |
Author | Mukhina, A. N. | |
Author | Losev, V. N. | |
Accessioned Date | 2020-01-20T07:54:35Z | |
Available Date | 2020-01-20T07:54:35Z | |
Issued Date | 2019-01 | |
Bibliographic Citation | Trofimchuk, A. K. Preconcentration and Determination of Nickel ions using Silica with Functional Groups of Sulfonic Derivatives of Nitroso Naphthols [Текст] / A. K. Trofimchuk, S. L. Didukh, A. N. Mukhina, V. N. Losev // Methods and objects of chemical analysis. — 2019. — Т. 14 (№ 1). — С. 30-36 | |
URI (for links/citations) | http://www.moca.net.ua/en/19/14_1_4m.html | |
URI (for links/citations) | https://elib.sfu-kras.ru/handle/2311/129081 | |
Description | Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. | |
Abstract | Silica based adsorbents modified with polyhexamethylene guanidine and sulfonic derivatives of nitroso naphthols
- nitroso-N salt (NNS) and nitroso-R salt (NRS), have been proposed for preconcentration and solid-phase
photometric determination of Ni(II) in industrial solutions. Adsorbents with the surface concentration of the reagents
of 1.5 and 3 μmol/g have been studied. Adsorbents with NNS functional groups quantitatively extract Ni(II) at pH
5.5-7.5, while with NRS functional groups – at pH 5.5-7.0, giving complex compounds with the composition
Ni(II) : Reagent = 1 : 3. After Ni(II) adsorption the adsorbents became orange (λ = 510 нм) or brown (λ = 490 нм)
for NNS and NRS respectively. The pH range of maximum color intensity coincides with the pH range of the
quantitative extraction of Ni(II). The procedure of solid-phase photometric determination of Ni(II) in form of diffuse
reflectance spectroscopy has been developed. The analytical range of the procedure is 0.1 – 3.0 μg of Ni(II)
per 0.1 g of the adsorbent with the surface concentration of the reagent of 1.5 μmol/g and 0.15 – 6 μg of Ni(II)
per 0.1g of the adsorbent with the surface concentration of the reagent of 3 μmol/g. The procedure was used
for determination of Ni(II) in the rinsing and waste waters of galvanic manufactory. The results accuracy was
confirmed by ICP-OES analysis. | |
Subject | nickel(II) | |
Subject | adsorption | |
Subject | preconcentration | |
Subject | silica | |
Subject | nitroso-R salt | |
Subject | nitroso-N salt | |
Subject | adsorption-photometric | |
Subject | determination | |
Title | Preconcentration and Determination of Nickel ions using Silica with Functional Groups of Sulfonic Derivatives of Nitroso Naphthols | |
Type | Journal Article | |
Type | Journal Article Postprint | |
Pages | 30-36 | |
GRNTI | 31.19.15 | |
Update Date | 2020-01-20T07:54:35Z | |
DOI | 10.17721/moca.2019.30-36 | |
Institute | Институт цветных металлов и материаловедения | |
Department | Кафедра композиционных материалов и физико-химии металлургических процессов | |
Department | Кафедра физической и неорганической химии | |
Journal Name | Methods and objects of chemical analysis | |
Journal Quartile in Scopus | Q4 | |
Journal Quartile in Web of Science | без квартиля | |