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Mechanism of dicarbonyl(2,4-pentanedionato)iridium(I) decomposition on iron surface and in gas phase: Complex experimental and theoretical study
Автор | Kovaleva, E. A. | |
Автор | Kuzubov, A. A. | |
Автор | Vikulova, E. S. | |
Автор | Basova, T. V. | |
Автор | Morozova N.B | |
Дата внесения | 2018-02-07T07:29:02Z | |
Дата, когда ресурс стал доступен | 2018-02-07T07:29:02Z | |
Дата публикации | 2017-06 | |
Библиографическое описание | Kovaleva, E. A. Mechanism of dicarbonyl(2,4-pentanedionato)iridium(I) decomposition on iron surface and in gas phase: Complex experimental and theoretical study [Текст] / E. A. Kovaleva, A. A. Kuzubov, E. S. Vikulova, T. V. Basova, Morozova N.B // Journal of Molecular Structure. — 2017. — Т. 1146. — С. 677-683 | |
ISSN | 00222860 | |
URI (для ссылок/цитирований) | http://www.sciencedirect.com/science/article/pii/S0022286017308402?via%3Dihub | |
URI (для ссылок/цитирований) | https://elib.sfu-kras.ru/handle/2311/69854 | |
Аннотация | The mechanism of thermal destruction of Ir(acac)(CO)2 as one of the most important MOCVD precursors for Ir coatings deposition was proposed on the footing of the in situ mass spectrometry analysis and quantum chemical modeling. Calculated structural parameters and vibrational spectra of Ir(acac)(CO)2 molecule were found to be in a fairly good agreement with the experimental data. Ir(acac)(CO)2 was found to unlikely decompose in the gaseous phase while its adsorption onto the iron surface leads to major structural distortions easing the bond cleavage, molecule decomposition with subsequent formation of iridium films. | |
Тема | Iridium films | |
Тема | MOCVD | |
Тема | Ir(acac)(CO)2 | |
Тема | Thermal decomposition | |
Тема | Mass spectrometry | |
Тема | Quantum chemical modeling | |
Название | Mechanism of dicarbonyl(2,4-pentanedionato)iridium(I) decomposition on iron surface and in gas phase: Complex experimental and theoretical study | |
Тип | Journal Article | |
Тип | Journal Article Preprint | |
Страницы | 677-683 | |
ГРНТИ | 31.15.27 | |
Дата обновления | 2018-02-07T07:29:02Z | |
DOI | 10.1016/j.molstruc.2017.06.059 | |
Подразделение | Научно-исследовательская часть | |
Журнал | Journal of Molecular Structure | |
Квартиль журнала в Scopus | Q3 | |
Квартиль журнала в Web of Science | Q3 |