A simple method for the preparation of 3,5-dinitrimino-1,2,4-triazole and its salts
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URI (для ссылок/цитирований):
http://hgs.osi.lv/index.php/hgs/article/view/3784/2999https://elib.sfu-kras.ru/handle/2311/70082
Дата:
2017-08Журнал:
Chemistry of Heterocyclic CompoundsКвартиль журнала в Scopus:
Q4Квартиль журнала в Web of Science:
Q3Библиографическое описание:
Astakhov, A. M. A simple method for the preparation of 3,5-dinitrimino-1,2,4-triazole and its salts [Текст] / A. M. Astakhov, D. V. Antishin, V. A. Revenko, A. D. Vasiliev, E. S. Buka // Chemistry of Heterocyclic Compounds. — 2017. — Т. 53 (6/7). — С. 1-6Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.
Аннотация:
The reaction of 2-methyl-1-nitrоisothiourea with hydrazine in the presence of alkali metal bicarbonates (carbonates) resulted in the formation of 3,5-dinitrimino-1,2,4-triazole salts. The same salts were also formed by a reaction of 2-methyl-1-nitrоisothiourea with alkali metal salts of 4-nitrоsemicarbazide. This represents the first synthesis and characterization of the high-energy 3,5-dinitrimino-1,2,4-triazole, which can be readily isolated by treatment of its disodium salt with HCl.