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Михалева, Е. А.
Флеров, И. Н.
Карташев, А. В.
Горев, М. В.
Молокеев, М. С.
Богданов, Е. В.
Бондарев, В. С.
Коротков, Л. Н.
Rysiakiewicz-Pasek, E.
2019-07-01T07:30:28Z
2019-07-01T07:30:28Z
2018-05
Михалева, Е. А. Effect of restricted geometry and external pressure on the phase transitions in ammonium hydrogen sulfate confined in a nanoporous glass matrix [Текст] / Е. А. Михалева, И. Н. Флеров, А. В. Карташев, М. В. Горев, М. С. Молокеев, Е. В. Богданов, В. С. Бондарев, Л. Н. Коротков, E. Rysiakiewicz-Pasek // Journal of Materials Science. — 2018. — Т. 53. — С. 12132-12144
00222461
https://link.springer.com/article/10.1007%2Fs10853-018-2467-1
http://elib.sfu-kras.ru/handle/2311/111566
A study of heat capacity, thermal dilatation, susceptibility to hydrostatic pressure, permittivity and polarization loops was carried out on NH4HSO4 – porous glass nanocomposites (AHS ? PG) as well as empty glass matrices. The formation of dendrite clusters of AHS with a size, dcryst, exceeding the pore size was found. An insignificant anisotropy of thermal expansion of AHS ? PG showing statistically uniform distribution of AHS with random orientations of nanocrystallites over the matrix was observed. The effect of internal and external pressures on thermal properties and permittivity was studied. At the phase transition P-1 $ Pc, a strongly nonlinear decrease in the entropy DS 2andvolumestrain(DV/V) T2 was observed with decreasing dcryst. The linear change in temperatures of both phase transitions P-1 $ Pc $ P21/c under hydrostatic pressure is accompanied by the expansion of the temperature range of existence of the ferroelectric phase Pc, while this interval narrows as dcryst decreases.
Ferroelectrics
Phase transitions
Effect of restricted geometry and external pressure on the phase transitions in ammonium hydrogen sulfate confined in a nanoporous glass matrix
Journal Article
Journal Article Preprint
12132-12144
29.19.35
2019-07-01T07:30:28Z
10.1007/s10853-018-2467-1
Институт инженерной физики и радиоэлектроники
Базовая кафедра физики твердого тела и нанотехнологий
Кафедра теплофизики
Journal of Materials Science
Q1
Q2


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