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Anomalous polarization dependence in vibrationally resolved resonant inelastic x-ray scattering of H2O
Автор | Vinícius Vaz, Da Cruz | |
Автор | Emelie, Ertan | |
Автор | Nina, Ignatova | |
Автор | Rafael C. Couto | |
Автор | Sergey, Polyutov | |
Автор | Michael, Odelius | |
Автор | Victor, Kimberg | |
Автор | Faris Gel’mukhanov | |
Дата внесения | 2019-07-01T07:28:02Z | |
Дата, когда ресурс стал доступен | 2019-07-01T07:28:02Z | |
Дата публикации | 2018-07 | |
Библиографическое описание | Vinícius Vaz, Da Cruz. Anomalous polarization dependence in vibrationally resolved resonant inelastic x-ray scattering of H2O [Текст] / Da Cruz Vinícius Vaz, Ertan Emelie, Ignatova Nina, Rafael C. Couto, Polyutov Sergey, Odelius Michael, Kimberg Victor, Faris Gel’mukhanov // PHYSICAL REVIEW A. — 2018. — № 98. — С. 012507 (7) | |
ISSN | 24699926 | |
URI (для ссылок/цитирований) | https://journals.aps.org/pra/abstract/10.1103/PhysRevA.98.012507 | |
URI (для ссылок/цитирований) | https://elib.sfu-kras.ru/handle/2311/111079 | |
Аннотация | It is well established that different electronic channels, in resonant inelastic x-ray scattering (RIXS), display different polarization dependences due to different orientations of their corresponding transition dipole moments in the molecular frame. However, this effect does not influence the vibrational progression in the Franck-Condon approximation. We have found that the transition dipole moments of core excitation and deexcitation experience ultrafast rotation during dissociation in the intermediate core-excited state. This rotation makes the vibrational progression in RIXS sensitive to the polarization of the x-ray photons.We study the water molecule, in which the effect is expressed in RIXS through the dissociative core-excited state where the vibrational scattering anisotropy is accompanied also by violation of parity selection rules for the vibrations. | |
Тема | RIXS | |
Тема | polarisation | |
Тема | water | |
Тема | H2O | |
Тема | core-excited state | |
Тема | Franck-Condon approximation | |
Название | Anomalous polarization dependence in vibrationally resolved resonant inelastic x-ray scattering of H2O | |
Тип | Journal Article | |
Тип | Journal Article Preprint | |
Страницы | 012507 (7) | |
ГРНТИ | 29.29 | |
Дата обновления | 2019-07-01T07:28:02Z | |
DOI | 10.1103/PhysRevA.98.012507 | |
Подразделение | Научно-исследовательская часть | |
Подразделение | Институт нанотехнологий, спектроскопии и квантовой химии | |
Журнал | PHYSICAL REVIEW A | |
Квартиль журнала в Scopus | Q1 | |
Квартиль журнала в Web of Science | Q1 |