Properties in CO Hydrogenation of the Nano-Catalysts Produced by Supporting Iron Carbonyls on SiO2

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http://elib.sfu-kras.ru/handle/2311/833
Author:
Kuznetsov, Boris N.
Kovalchuk, Vladimir I.
Mikova, Nadezhda M.
Chesnokov, Nikolai V.
Naimushina, Liliya V.
(Boris N. Kuznetsov, Nikolai V. Chesnokov: Siberian Federal University, 79 Svobodny, Krasnoyarsk, 660041 Russia, Institute of Chemistry and Chemical Technology SB RAS, Akademgorodok, Krasnoyarsk, 660036 Russia, e-mail: bnk@icct.ru; Vladimir I. Kovalchuk: Pittsburg University, PA 15261 USA; Nadezhda M. Mikova: Institute of Chemistry and Chemical Technology SB RAS, Akademgorodok, Krasnoyarsk, 660036 Russia; Liliya V. Naimushina: Krasnoyarsk State Institute of Economics and Trade, 2 L. Prushinskaya st., Krasnoyarsk, 660075 Russia)
Date:
2008-11
Abstract:
There have been studied the catalytic properties in the reaction of CO hydrogenation of nano-catalysts produced by supporting on silica the iron carbonyl compounds containing various numbers of metal atoms. It was determined that the catalytic activity of the supported carbonyls increases with the rise of the number of the metal atoms in their composition. Some of them have a very high selectivity in respect to the C2-C3 olefins.
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