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Coordination model, stability constants, and kinetics study of cystamine and L-cystine with [PdCl4](2-) in hydrochloric aqueous solutions
Stoichiometry, equilibria, and kinetics of [PdCl4](2-) interactions with l-cystine (H(4)CysS(2+)) and cystamine (H(2)Cyst(2+)) have been investigated spectrophotometrically in strong hydrochloric acidic media. Interactions ...
Influence of alkyl substituents in 1,3-diethyl-2-thiobarbituric acid on the coordination environment in M(H2O)(2)(1,3-diethyl-2-thiobarbiturate)(2) M = Ca2+, Sr2+
Two new isostructural complexes, [Ca(H2O)(2) (mu(2)-Detba-O,O')(2)](n) (1) and [Sr(H2O)(2)(mu(2)-Detba-O,O')(2)](n) (2) (HDetba = 1,3-diethyl-2-thiobarbituric acid), were synthesized and characterized by single-crystal and ...