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Crystal structure of [Bi(N-ethylthiourea)(4)(ClO4)(2)]ClO4
The structure of the bismuth(III) complex with N-ethylthiourea (Ettu) has been determined for the first time. We found that the crystal structure of [Bi(Ettu)(4)(ClO4)(2)]ClO4 is built of distorted octahedral cations ...
First outer-sphere 1,3-diethyl-2-thiobarbituric compounds [M(H2O)(6)] (1,3-diethyl-2-thiobarbiturate)(2)center dot 2H(2)O (M = Co2+, Ni2+): Crystal structure, spectroscopic and thermal properties
Two new d-element compounds, [Co(H2O)(6)](Detba)(2)center dot 2H(2)O (1) and [Ni(H2O)(6)](Detba)(2)center dot 2H(2)O (2) (HDetba - 1,3-diethyl-2-thiobarbituric acid) were synthesized and characterized by single-crystal and ...
Electrocontact Material Based on Silver Dispersion-Strengthened by Nickel, Titanium, and Zinc Oxides
Samples of a composite electrocontact material based on silver strengthened by the dispersed phases of zinc and titanium oxides have been investigated by the electron microscopy and energy dispersive X-ray spectroscopy. A ...
Coordination effects in hydrated manganese(II) 1,3-diethyl-2-thiobarbiturates and their thermal stability
Three new complexes of 1,3-diethyl-thiobarbituric acid (HDetba), barbiturate-bridged 2D Mn(II) polymer [Mn(H2O)2(Detba)2] (1), trinuclear [Mn3(H2O)10(Detba)6] (2) and discrete molecular [Mn(H2O)4(Detba)2]·H2O (3) are ...
Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)
The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals ...
A key role of tensile strain and surface termination in formation and properties of La0.7Sr0.3MnO3 composites with carbon nanotubes
Atomic and electronic structure of LSMO-based composites with carbon nanotubes were studied by means of density functional theory with respect to the termination of LSMO surface. The deformation of the tubes caused by the ...