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Golovnev, N. N.
Molokeev, M. S.
Smolentsev, A. I.
Lesnikov, M. K.
2018-02-07T07:33:12Z
2018-02-07T07:33:12Z
2017-02
Golovnev, N. N. Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II) [Текст] / N. N. Golovnev, M. S. Molokeev, A. I. Smolentsev, M. K. Lesnikov // Russian Journal of Coordination Chemistry. — 2017. — Т. 43 (№ 2). — С. 82-85
10703284
https://link.springer.com/article/10.1134%2FS1070328417010031
http://elib.sfu-kras.ru/handle/2311/70172
Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала.
The structure of the dimeric complex [Co2(BuOH)4(Detba)4] (I), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) Å, β = 92.196(2)°, V = 2996.1(3) Å3, space group P21/c, Z = 2. The Co2+ ions in compound I are joined in pairs by bridging ligands μ2-Detba–−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО5. Hydrogen bonds O–H···O formed by BuOH and Detba– join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.
Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)
Journal Article
Journal Article Preprint
82-85
31.17.29
2018-02-07T07:33:12Z
10.1134/S1070328417010031
Институт цветных металлов и материаловедения
Научно-исследовательская часть
Кафедра физической и неорганической химии
Russian Journal of Coordination Chemistry
Q3
Q4


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