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Evgeniya, Moshkina
Yurii, Seryotkin
Asya, Bovina
Maxim, Molokeev
Evgeniy, Eremin
Nadejda, Belskaya
Leonard, Bezmaternykh
2020-01-20T07:16:23Z
2020-01-20T07:16:23Z
2018-12
Evgeniya, Moshkina. Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3 [Текст] / Moshkina Evgeniya, Seryotkin Yurii, Bovina Asya, Molokeev Maxim, Eremin Evgeniy, Belskaya Nadejda, Bezmaternykh Leonard // Journal of Crystal Growth. — 2018. — Т. 503. — С. 1-8
00220248
https://www.sciencedirect.com/science/article/pii/S0022024818304305
https://elib.sfu-kras.ru/handle/2311/128866
The high-temperature crystallizing phases of fluxes (molten solutions) based on Bi2O3:MoO3=1:3 and diluted by Na2CO3, B2O3 (under varying of Na2CO3:B2O3) and CuO and Mn2O3 (0≤Mn2O3:CuO≤5) are studied. The conditions of the stable crystallization of Mn2+1-xCuxMoO4, Mn23+O3, Mn2+Mn23+O4, Mn2+1-xCuxMn3+BO4 and Mn2+2-xCuxMn3+BO5 have been found. The influence of MoO3 and Na2CO3 to the crystallization processes of Mn2+- and Mn3+-containing Mn2+1-xCuxMoO4 and Mn2+Mn23+O4 and Mn23+O3 are clarified. The occurrence of the chemical bonds of these types at the crystallization of Mn-heterovalent Mn2+1-xCuxMn3+BO4 and Mn2+2-xCuxMn3+BO5 oxyborates is studied. Single crystal growth techniques of these oxyborates are suggested. The results of structural and magnetic characterization of some discussed compounds are presented.
Crystal formation of Cu-Mn-containing oxides and oxyborates in bismuth-boron fluxes diluted by MoO3 and Na2CO3
Journal Article
Journal Article Preprint
1-8
29.19
2020-01-20T07:16:23Z
10.1016/j.jcrysgro.2018.09.011
Институт инженерной физики и радиоэлектроники
Базовая кафедра физики твердого тела и нанотехнологий
Journal of Crystal Growth
Q2
Q3


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