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One-step immobilization of cesium and strontium from alkaline solutions via a facile hydrothermal route
Автор | Tatiana A. Vereshchagina | |
Автор | Ekaterina A. Kutikhina | |
Автор | Yana, Yu Chernykh | |
Автор | Leonid A. Solovyov | |
Автор | Anatoly M. Zhizhaev | |
Автор | Sergei N. Vereshchagin | |
Автор | Аншиц, А. Г. | |
Дата внесения | 2019-07-01T07:29:25Z | |
Дата, когда ресурс стал доступен | 2019-07-01T07:29:25Z | |
Дата публикации | 2018-11 | |
Библиографическое описание | Tatiana A. Vereshchagina. One-step immobilization of cesium and strontium from alkaline solutions via a facile hydrothermal route [Текст] / Tatiana A. Vereshchagina, Ekaterina A. Kutikhina, Yu Chernykh Yana, Leonid A. Solovyov, Anatoly M. Zhizhaev, Sergei N. Vereshchagin, А. Г. Аншиц // Journal of Nuclear Materials. — 2018. — Т. 510. — С. 243-255 | |
ISSN | 00223115 | |
URI (для ссылок/цитирований) | https://www.sciencedirect.com/science/article/pii/S0022311518305439 | |
URI (для ссылок/цитирований) | https://elib.sfu-kras.ru/handle/2311/111358 | |
Описание | Текст статьи не публикуется в открытом доступе в соответствии с политикой журнала. | |
Аннотация | Hydrothermal treatment of coal fly ash cenospheres (Si/Al = 2.7) as a glassy source of Si and Al was carried out in 1.5 M NaOH at 150°C in the presence of Cs+ and Sr2+ to study the possibility of Cs+ and Sr2+ immobilization in mineral-like compounds. Systems Na2O–H2O– (SiO2–Al2O3) glass, Na2O–Cs2O–H2O– (SiO2–Al2O3) glass with Cs+/Na+ ratios of 0.05 and 0.5, and Na2O–SrO–H2O– (SiO2–Al2O3) glass with Sr2+/Na+ ratios of 0.25 and 0.025 were under study. Structure, composition and morphology of solid products were characterized by PXRD, SEM-EDS and STA methods. In the Cs+/Sr2+ free systems the deep crystallization of cenosphere glass takes place resulting in hollow polycrystalline analcime microspheres. Microsphere solids including phases of ANA topology (analcime, pollucite or analcime-pollucite solid solutions) and Cs+/Sr2+ silicates are produced as Cs+ and Sr2+ immobilized forms in the Cs+/Sr2+ bearing systems. The degree of Cs+ and Sr2+ recovery from alkaline solutions was 90–99%. | |
Тема | Analcime | |
Тема | Pollucite | |
Тема | Cenospheres | |
Тема | Hydrothermal synthesis | |
Тема | Radioactive waste | |
Название | One-step immobilization of cesium and strontium from alkaline solutions via a facile hydrothermal route | |
Тип | Journal Article | |
Тип | Published Journal Article | |
Страницы | 243-255 | |
ГРНТИ | 31.15 | |
Дата обновления | 2019-07-01T07:29:24Z | |
DOI | 10.1016/j.jnucmat.2018.08.015 | |
Институт | Политехнический институт | |
Подразделение | Кафедра химии | |
Журнал | Journal of Nuclear Materials | |
Квартиль журнала в Scopus | Q1 | |
Квартиль журнала в Web of Science | Q1 |